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Grazing‐incidence X‐ray scattering (GIXS) is widely used to analyze the crystallinity and nanoscale structure in thin polymer films. However, ionizing radiation will generate free radicals that initiate crosslinking and/or chain scission, and structural damage will impact the ordering kinetics, thermodynamics, and crystallinity in many polymers. We report a simple methodology to screen for beam damage that is based on lithographic principles: films are exposed to patterns of X‐ray radiation, and changes in polymer structure are revealed by immersing the film in a solvent that dissolves the shortest chains. The experiments are implemented with high throughput using the standard beam line instrumentation and a typical GIXS configuration. The extent of damage (at a fixed radiation dose) depends on a range of intrinsic material properties and experimental variables, including the polymer chemistry and molecular weight, exposure environment, film thickness, and angle of incidence. The solubility switch for common polymers is detected within 10–60 s at ambient temperature, and we verified that this first indication of damage corresponds with the onset of network formation in glassy polystyrene and a loss of crystallinity in polyalkylthiophenes. Therefore, grazing‐incidence X‐ray “patterning” offers an efficient approach to determine the appropriate data acquisition times for any GIXS experiment. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1074–1086  相似文献   
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对平行平板双光路横向剪切干涉仪的装调进行了研究,提出了一种矫正两个平行平板之间角度误差的方法.输出激光的波前采用Zernike多项式拟合,经过理论推导,发现两个方向差分波前求解出的倾斜像散之差与平行平板的角度误差存在线性关系,利用两个方向倾斜像散之差来矫正两个平行平板之间的角度误差.在平行平板横向剪切干涉仪的装调过程中使两个方向差分波前的倾斜像散之差为零即可以使两个方向的平行平板之间的角度误差值为零.进一步地从实验上证明了这个线性关系,对于所用的实验系统,当离焦像差为-3.224 7±0.001 8,两个方向差分波前的倾斜像散之差波动范围为±2.0×10^-3时,平行平板的角度误差可以控制在8.82″之内,高阶像差对平行平板的角度误差调节精度的影响约为1.63″.该方法具有装调简单、精确度高,易于流程化操作的优点.  相似文献   
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研究了一类具有非线性发生率和时滞的随机SIQR计算机病毒模型.首先证明了该系统具有唯一的全局正解,然后通过构造适当的Lyapunov函数并利用伊藤公式,分析了该模型的解在无病平衡点附近及地方病平衡点附近的渐近行为,最后通过数值模拟对随机系统解的渐近行为做了进一步的分析并给出了结论.  相似文献   
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Oblique perforation of thick metallic plates by rigid projectiles with various nose shapes is studied in this paper. Two perforation mechanisms, i.e., the hole enlargement for a sharp projectile nose and the plugging formation for a blunt projectile nose, are considered in the proposed analytical model. It is shown that the perforation of a thick plate is dominated by several non-dimensional numbers, i.e., the impact function, the geometry function of projectile, the non-dimensional thickness of target and the impact obliquity. Explicit formulae are obtained to predict the ballistic limit, residual velocity and directional change for the oblique perforation of thick metallic plates. The proposed model is able to predict the critical condition for the occurrence of ricochet. The proposed model is validated by comparing the predictions with other existing models and independent experimental data.The English text was polished by Keren Wang  相似文献   
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在对 6种刹车盘和 2种刹车块材料组成的摩擦副进行变温摩擦磨损试验的基础上 ,将灰色关联法引入刹车副材料的筛选 ;在综合分析刹车副材料各性能指标的基础上 ,将待筛选的刹车副材料的摩擦学性能用灰色关联度进行量化 ;通过比较各刹车副关联度大小 ,用定量排序法对各刹车副材料的性能作出综合评价 ,从而筛选出性能优良的刹车副摩擦材料 .结果表明 ,B堆焊材料是最优的刹车盘材料 ,K2 刹车块材料可作为最优的刹车块材料 ,刹车副 P2 0 ,B/ K2 、P3 5,B/ K2 为筛选出的最优刹车副材料  相似文献   
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Studies on the oblique interactions of weakly nonlinear long waves in dispersive systems are surveyed. We focus mainly our concentration on the two-dimensional interaction between solitary waves. Two-dimensional Benjamin–Ono (2DBO) equation, modified Kadomtsev–Petviashvili (MKP) equation and extended Kadomtsev–Petviashvili (EKP) equation as well as the Kadomtsev–Petviashvili (KP) equation are treated. It turns out that a large-amplitude wave can be generated due to the oblique interaction of two identical solitary waves in the 2DBO and the MKP equations as well as in the KP-II equation. Recent studies on exact solutions of the KP equation are also surveyed briefly.  相似文献   
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The Isodyne technique based on the scattered light scanning from a thin laser beam can be used to obtain the information inside the loaded object in the room temperature nondestructively, so it is a very powerful technique in 3D stress analysis. The problems are how to interpret the information and how to get sufficient information from the few interference fringe. Birefringence phase shift technique can distinguish the fringe orders automatically and enrich the information in 256 gray levels between maxim and minim light intensity. In the paper the Isodyne birefringence phase shift method with an oblique incidence and equilibrium equation is presented, by which the 3D stresses in the middle plane of a plate with U shape notch are separated successfully. The project supported by the National Natural Science Foundation of China under the Grant No. 1380345  相似文献   
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